I'm a guy, and though I only have a few BPAL scents, I do wear O and Water of Notre Dame from time to time. I get a lot of compliments, particularly with Water of Notre Dame. Once in a while I'll throw on Neo-Tokyo.
The only ones I've smelled that I would absolutely NOT wear are Cockaigne (dear lord it's so sweeeet!) and Grand Guignol, but I've smelled very few, so as I continue my BPAL education, no doubt this list will expand.
My next batch of imps will be Antony, Oberon, Robin Goodfellow, Cthulhu, and Haunted. They all sound spectacular.